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Physical and chemical processes of wintertime secondary nitrate aerosol formation

Qi YING

Frontiers of Environmental Science & Engineering 2011, Volume 5, Issue 3,   Pages 348-361 doi: 10.1007/s11783-011-0343-1

Abstract: In the nighttime hours, both the gas phase N O reactions with water vapor and the N O heterogeneous

Keywords: secondary nitrate aerosol     N<sub>2sub>O<sub>5sub> heterogeneous reaction     process analysis    

Atmospheric heterogeneous reaction of chlorobenzene on mineral -FeO particulates: a chamber experiment

Frontiers of Environmental Science & Engineering 2023, Volume 17, Issue 11, doi: 10.1007/s11783-023-1734-9

Abstract:

● Photochemical conversion of chlorobenzene (CB) on α-Fe<sub>2sub>O<sub>3sub> was evaluated.

Keywords: Photochemical conversion     Chlorobenzene     α-Fe<sub>2sub>O<sub>3sub>     PCDD/Fs     Mineral particulate    

Enhancing the aromatic selectivity of cyclohexane aromatization by CO<sub>2sub> coupling

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 11,   Pages 1801-1808 doi: 10.1007/s11705-023-2325-9

Abstract: Herein, CO<sub>2sub> is introduced into the cyclohexane conversion process on the HZSM-5 zeolite, whichBy optimizing the reaction conditions, an improved aromatic (benzene, toluene, xylene, and C<sub>9+sub>) selectivity of 48.2% can be obtained at the conditions of 2.7 MPa (CO<sub>2sub>), 450 °C, and1.7 h−1, which is better than that without CO<sub>2sub> (aromatic selectivity = 43.2%).>2sub>.

Keywords: aromatics     carbon dioxide     aromatization     coupling reaction     ZSM-5 zeolite    

Heterogeneous reaction mechanism of gaseous HNO

Nan ZHAO,Qingzhu ZHANG,Wenxing WANG

Frontiers of Environmental Science & Engineering 2016, Volume 10, Issue 5, doi: 10.1007/s11783-016-0836-z

Abstract: We studied the heterogeneous reaction mechanism of gaseous HNO with solid NaCl.HCl is released from heterogeneous reactions between gaseous HNO and solid NaCl.Water molecules induce surface reconstruction of NaCl to facilitate the reaction.This paper aimed at the heterogeneous reaction between gaseous HNO and solid NaCl.reaction.

Keywords: Seasalt particles     NaCl     HNO<sub>3sub>     Heterogeneous reaction     Reaction mechanism     Density functional theory    

Experimental study on the CO<sub>2sub> foam injecting way of profile control and flooding in heterogeneous

Zhao Jinsheng,Tan Junling,Gu Zhengfu,Liu Xiaochun

Strategic Study of CAE 2012, Volume 14, Issue 11,   Pages 88-93

Abstract: the foaming agent optimization result, using parallel cores with approximate permeability contrast,CO2foam flooding experiment was simulated through 2 injection way.The experiment result showed that underground foaming way, CO2 and the foaming agent injected alternatelyinjection slug combination was first 0.2 PV (pore volume) foaming agent solution and then 0.4 PV CO2

Keywords: heterogeneous reservoirs     CO<sub>2sub> foam     profile control and flooding     injection parameter     experimental    

In-MOF-derived In<sub>2sub>S<sub>3sub>/Bi<sub>2sub>S<sub>3sub> heterojunction for enhanced photocatalytic

Frontiers in Energy 2023, Volume 17, Issue 5,   Pages 654-663 doi: 10.1007/s11708-023-0885-5

Abstract: In this paper, a broad spectrum responsive In<sub>2sub>S<sub>3sub>/Bi<sub>2sub>S<sub>3sub> heterojunctionis constructed by in-situ integrating Bi<sub>2sub>S<sub>3sub> with the In<sub>2sub>S<subsynergistic effect of wide-spectrum response, effective charge separation and transfer, and strong heterogeneousinterfacial contacts, the In<sub>2sub>S<sub>3sub>/Bi<sub>2sub>S<sub>3sub> heterojunction demonstrates> (0.32 mmol/(g∙h) and Bi<sub>2sub>S<sub>3sub> (0.41 mmol/(g∙h)), respectively.

Keywords: photocatalytic hydrogen production     wide-spectrum response     metal sulfides     MOFs derivative     heterogeneous    

Thermodynamic Analysis and Reaction Model of Combustion Synthesis in Al-Cr<sub>2sub>O<sub>3sub> Systemwith Al<sub>2sub>O<sub>3sub> and Cr<sub>2sub>O<sub>3sub> Diluents

Zhang Yancheng,Pan Ye,Zhang Chuan

Strategic Study of CAE 2004, Volume 6, Issue 6,   Pages 63-67

Abstract:

The thermodynamic calculation and analysis of combustion synthesis reaction of Al - Cr<sub>2</sub>O<sub>3</sub> system with AI<sub>2</sub>O<sub>3</sub>and Cr<sub>2</sub>O<sub>3</sub> diluents were conducted, and the effects of reactionstarting temperature T<sub>O</sub>, diluents AI<sub>2</sub>O<sub>3</sub> and Cr<sub>2</sub>O<sub>3</sub> on the adiabatic combustion temperature

Keywords: cermet     combustion synthesis     Al - Cr<sub>2sub>O<sub>3sub> system     thermodynamics     reaction model    

Events and reaction mechanisms during the synthesis of an Al

M. ABDELLAHI, M. ZAKERI, H. BAHMANPOUR

Frontiers of Chemical Science and Engineering 2013, Volume 7, Issue 2,   Pages 123-129 doi: 10.1007/s11705-013-1325-6

Abstract: The composite started to form at milling times of 9–10 h but the reaction was not complete.

Keywords: ball milling     nanocomposite     Al<sub>2sub>O<sub>3sub>     TiB<sub>2sub>    

>In situ growth of phosphorized ZIF-67-derived amorphous CoP/Cu<sub>2sub>O@CF electrocatalystfor efficient hydrogen evolution reaction

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10,   Pages 1430-1439 doi: 10.1007/s11705-023-2320-1

Abstract: heterojunction on a self-supporting copper foam (CF) substrate with excellent performance for hydrogen evolution reactionThe intermediate product was phosphorized to obtain final electrocatalyst (CoP/Cu<sub>2sub>O@CF) withThe electrochemical measurement proved that CoP/Cu<sub>2sub>O@CF catalyst exhibited excellent HER activitywas only 62 mV with the Tafel slope of 83 mV·dec–1 at a current density of 10 mA·cm2sub>2sub>O@CF catalyst, which will act as

Keywords: CoP/Cu<sub>2sub>O@CF     electrocatalyst     phosphorization     HER     DFT    

Characterization and performance of V

Caiting LI, Qun LI, Pei LU, Huafei CUI, Guangming ZENG

Frontiers of Environmental Science & Engineering 2012, Volume 6, Issue 2,   Pages 156-161 doi: 10.1007/s11783-010-0295-x

Abstract: The best catalyst yielded above 80% NO conversion in the reaction temperature range of 160°C–300°C.

Keywords: V<sub>2sub>O<sub>5sub>/CeO<sub>2sub> catalysts     NH<sub>3sub>-SCR (selective catalytic reduction    

On the monolayer dispersion behavior of Co<sub>3sub>O<sub>4sub> on HZSM-5 support: designing applicable

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 11,   Pages 1741-1754 doi: 10.1007/s11705-023-2332-x

Abstract: It has been revealed that the quantities of surface active oxygen (O<sub>2sub>) and acidsites are crucial for the reaction, which can adsorb and activate NO<sub>xsub> and NH<sub>3reaction performance. 4% Co<sub>3sub>O<sub>4sub>/ZSM-5, the catalyst close to the monolayer dispersioncapacity, possesses the most abundant active O<sub>2sub> species and acidic sites, therebycapacity amount of Co<sub>3sub>O<sub>4sub> onto HZSM-5 support.

Keywords: Co<sub>3sub>O<sub>4sub>/ZSM-5     NO<sub>xsub>-SCR by NH<sub>3sub>     monolayer dispersionthreshold effect     surface acid sites     surface active O<sub>2sub> anions    

Chemical deactivation of V

Xiaodong WU, Wenchao YU, Zhichun SI, Duan WENG

Frontiers of Environmental Science & Engineering 2013, Volume 7, Issue 3,   Pages 420-427 doi: 10.1007/s11783-013-0489-0

Abstract: V O -WO /TiO catalyst was poisoned by impregnation with NH Cl, KOH and KCl solution, respectively. The catalysts were characterized by X-ray diffraction (XRD), inductively coupled plasma (ICP), N physisorption, Raman, UV-vis, NH adsorption, temperature-programmed reduction of hydrogen (H -TPR), temperature-programmed oxidation of ammonia (NH -TPO) and selective catalytic reduction of NO with ammonia (NH -SCR). The deactivation effects of poisoning agents follow the sequence of KCl>KOH>>NH Cl. The addition of ammonia chloride enlarges the pore size of the titania support, and promotes the formation of highly dispersed V=O vanadyl which improves the oxidation of ammonia and the high-temperature SCR activity. K ions are suggested to interact with vanadium and tungsten species chemically, resulting in a poor redox property of catalyst. More importantly, potassium can reduce the Br?nsted acidity of catalysts and decrease the stability of Br?nsted acid sites significantly. The more severe deactivation of the KCl-treated catalyst can be mainly ascribed to the higher amount of potassium resided on catalyst.

Keywords: V<sub>2sub>O<sub>5sub>-WO<sub>3sub>/TiO<sub>2sub>     potassium chloride     poisoning     reducibility     acid    

Preparation of Cu/ZrO

Xinmei LIU, Shaofen BAI, Huidong ZHUANG, Zifeng YAN

Frontiers of Chemical Science and Engineering 2012, Volume 6, Issue 1,   Pages 47-52 doi: 10.1007/s11705-011-1170-4

Abstract: synthesis from CO /H were respectively prepared by deposition coprecipitation (DP) and solid state reaction

Keywords: Cu/ZrO<sub>2sub>     methanol synthesis     deposition coprecipitation     solid state reaction     CO<sub>2sub>/H<sub>2sub>    

Simultaneous removal of NO and chlorobenzene on VO/TiO granular catalyst: Kinetic study and performance prediction

Frontiers of Environmental Science & Engineering 2021, Volume 15, Issue 4, doi: 10.1007/s11783-020-1363-5

Abstract:

• A V<sub>2sub>O<sub>5sub>/TiO<sub>2sub> granular catalyst for

Keywords: NO<sub>xsub>     Chlorobenzene     Simultaneous removal     Kinetic study     Performance prediction     V<sub>2sub>O<sub>5sub>/TiO<sub>2sub>     Graphical abstract    

CeO doping boosted low-temperature NH-SCR activity of FeTiO catalyst: A microstructure analysis and reaction

Frontiers of Environmental Science & Engineering 2022, Volume 16, Issue 5, doi: 10.1007/s11783-022-1539-2

Abstract:

• CeO<sub>2sub> doping significantly improved low-temperature NH<sub>3sub>-SCR activity on FeTiO<sub>xsub>.

Keywords: NH<sub>3sub>-SCR     CeO<sub>2sub> doping     Low-temperature NO<sub>xsub> removal     Improved redox    

Title Author Date Type Operation

Physical and chemical processes of wintertime secondary nitrate aerosol formation

Qi YING

Journal Article

Atmospheric heterogeneous reaction of chlorobenzene on mineral -FeO particulates: a chamber experiment

Journal Article

Enhancing the aromatic selectivity of cyclohexane aromatization by CO<sub>2sub> coupling

Journal Article

Heterogeneous reaction mechanism of gaseous HNO

Nan ZHAO,Qingzhu ZHANG,Wenxing WANG

Journal Article

Experimental study on the CO<sub>2sub> foam injecting way of profile control and flooding in heterogeneous

Zhao Jinsheng,Tan Junling,Gu Zhengfu,Liu Xiaochun

Journal Article

In-MOF-derived In<sub>2sub>S<sub>3sub>/Bi<sub>2sub>S<sub>3sub> heterojunction for enhanced photocatalytic

Journal Article

Thermodynamic Analysis and Reaction Model of Combustion Synthesis in Al-Cr<sub>2sub>O<sub>3sub> Systemwith Al<sub>2sub>O<sub>3sub> and Cr<sub>2sub>O<sub>3sub> Diluents

Zhang Yancheng,Pan Ye,Zhang Chuan

Journal Article

Events and reaction mechanisms during the synthesis of an Al

M. ABDELLAHI, M. ZAKERI, H. BAHMANPOUR

Journal Article

>In situ growth of phosphorized ZIF-67-derived amorphous CoP/Cu<sub>2sub>O@CF electrocatalystfor efficient hydrogen evolution reaction

Journal Article

Characterization and performance of V

Caiting LI, Qun LI, Pei LU, Huafei CUI, Guangming ZENG

Journal Article

On the monolayer dispersion behavior of Co<sub>3sub>O<sub>4sub> on HZSM-5 support: designing applicable

Journal Article

Chemical deactivation of V

Xiaodong WU, Wenchao YU, Zhichun SI, Duan WENG

Journal Article

Preparation of Cu/ZrO

Xinmei LIU, Shaofen BAI, Huidong ZHUANG, Zifeng YAN

Journal Article

Simultaneous removal of NO and chlorobenzene on VO/TiO granular catalyst: Kinetic study and performance prediction

Journal Article

CeO doping boosted low-temperature NH-SCR activity of FeTiO catalyst: A microstructure analysis and reaction

Journal Article